Can the Metal “Tantalum” be Used for Rings?

Can the Metal “Tantalum” be Used for Rings?

Can the metal “tantalum” be used for rings?

Yes, it can.

Tantalum is extremely resistant to corrosion and does not react to hydrochloric acid, concentrated nitric acid, or aqua regia in either cold or hot conditions.

tantalum rings

Tantalum’s pro-biological properties make it medically useful for making thin sheets or threads to mend damaged tissue. It is also harmless to the human body when made into rings and jewelry, and can be worn without worry.

Tantalum itself is harmless to humans and is as biophilic as silver, titanium, niobium, and other metals. However, tantalum and niobium may be mixed with rare earth elements during the smelting and extraction process, resulting in a little radioactivity, but pure tantalum is very safe.

Tantalum and niobium -a symbol of love?

Niobium and tantalum are in the same group in the periodic table and have very similar physical and chemical properties. In nature, they are often “inseparable”, like a pair of “twins”. When niobium and tantalum were discovered in the early 19th century, they were thought to be one element, and it was only after about 42 years that they were separated for the first time by chemical analysis, and it became clear that they were two different metallic elements.

Tantalum (Ta) niobium (Nb) are high melting point (tantalum 2996 ° C, niobium 2468 ° C), high boiling point (tantalum 5427 °C, niobium 5127 °C) rare metals, the appearance of steel-like, gray-white luster, powder dark gray, with gas absorption, corrosion resistance, superconductivity, unipolar conductivity and high strength at high temperatures, and other characteristics.

Therefore, the current tantalum niobium new material applications related to high-tech industrial fields include electronics, precision ceramics, and precision glass industry; electro-acoustic optical devices; cemented carbide, astronautics, and electronic energy industry; biomedical engineering; superconductivity industry; special steel and other industries.

Niobium-tantalum has good resistance to physiological corrosion and biocompatibility and does not interact with body tissues, so it is often used in the manufacture of bone plates, skull plate bone screws, dental implant roots, surgical appliances, etc. Tantalum is also known as a “biophilic metal” because it replaces bone in the human body with tantalum strips on which muscles can grow.

This is why they are also known as a “pro-biological metal”. Therefore, there are no allergies when using them for rings, and the price is better. Because tantalum is almost twice as dense as niobium, a tantalum ring of the same size will be more textured, darker in color, and more expensive than a niobium ring.

Because they have always coexisted in nature, we can also define them as a good brother or a loving couple, if you want to buy a pair of rings you can consider buying one each of tantalum and niobium, which has a better meaning!

Ten Metals with the Highest Melting Points on Earth!

Ten Metals with the Highest Melting Points on Earth!

Tungsten and tungsten wire bulbs have the highest melting points of all metals. In addition, do you know which metal elements have melting points?

highest melting points metal

This article will take a look at the top ten metals with the highest melting points.

Tungsten

Tungsten is a silvery-white metal shaped like steel. It has the highest melting point of any metal element, up to 3422°C, and a boiling point of 5927°C, making it the highest melting point in the world. It is an ultra-high temperature-resistant metal, ranking first in the list of metals with the highest melting points. As a rare high melting point metal, tungsten is commonly used as a lamp filament because when an electric lamp is turned on, the filament reaches temperatures of up to 3000°C. Only tungsten can withstand such high temperatures. In addition, tungsten increases the high-temperature hardness of steel. Meanwhile, tungsten is widely used in the alloy, electronic and chemical industries because of its high melting point, high hardness, high density, and good electrical conductivity. At present, more than 20 kinds of tungsten minerals and tungsten-bearing minerals have been found on the earth.

Rhenium

Rhenium is a silvery-white rare metal with a high melting point. It has the second highest melting point of all metals, second only to tungsten. Its melting point is as high as 3180℃ and its boiling point is 5900℃. Because of its high melting point, rhenium is more difficult to obtain than diamonds and is one of the rarest elements in the earth’s crust, making it very expensive and among the most expensive metals in the world. Rhenium and its alloys are widely used in the aerospace, electronics industry, petrochemicals, and other fields, especially in high-efficiency jet engines and rocket engines, and are therefore of great importance in military strategy.

high melting metal

Osmium

Osmium is a high-density rare metal, belonging to the heavy platinum group of metals, and is the world’s highest density metal. Osmium is found in osmium-iridium ores, which are extremely difficult to mine because of their density of 22.48 g/cm3, a high melting point of 3045°C, and a boiling point above 5027°C, making them one of the three metals with the highest melting points in the world. Osmium has a wide range of applications and can be used to make ultra-hard alloys. It is mainly used as a catalyst in the industry. It is often used to make products with other metals to extend their life.

Tantalum

Tantalum is a rare metal mineral resource found mainly in tantalite, which coexists with niobium. With a density of 16.68 g/cm³, a melting point of 2980°C, and a boiling point of 5425°C, it is the fourth most insoluble metal after tungsten, rhenium, and osmium. As a rare metal, tantalum has a high melting point, low vapor pressure, good cold processing performance, high chemical stability, and strong resistance to liquid metal corrosion, and has a wide range of application prospects. It has important applications in high-tech fields such as electronics, metallurgy, steel, chemical industry, cemented carbide, atomic energy, superconductivity technology, automotive electronics, aerospace, and medical and scientific research. Almost half of the world’s tantalum metal production is used to produce tantalum capacitors.

Molybdenum

Molybdenum is a transition metal element. It is an essential trace element for humans, animals, and plants. It is also the metal element with the highest melting point. It has a density of 10.2 g/cm³, a melting point of 2610°C, and a boiling point of 5560°C. Molybdenum is a silvery-white metal that is hard and tough. Like tungsten, it is a refractory and rare metal. According to worldwide molybdenum consumption statistics, molybdenum still occupies the most important position in the steel industry, accounting for about 80 percent of total molybdenum consumption, followed by the chemical industry, which accounts for about 10 percent. In addition, molybdenum is also used in medicine, agriculture, and electrical and electronic technology, which accounts for about 10 percent of total consumption.

Niobium

What metal has the highest melting point? Niobium is one of the metals with the highest melting point in the world. Niobium is a silvery gray, soft, and ductile rare high melting point metal with a density of 8.57 g/cm³, a melting point of 2477°C, and a boiling point of 4744°C. At room temperature, niobium does not react with air, but at high temperatures, it combines directly with sulfur, nitrogen, and carbon. Niobium has good superconductivity, corrosion resistance, high melting point, and wear resistance and is widely used in steel, superconducting materials, aerospace, electronics industry, medical, and other fields. Niobium does not occur in nature in its pure state but is combined with other elements to form minerals. Brazil and Canada are still the largest producers of niobium concentrates.

Iridium

Iridium is extremely chemically stable in acids and is insoluble in acids. It is the most corrosion-resistant metal and the metal material with the highest melting point. Its density is 22.56 g/cm³, melting point 2450°C, and boiling point 4130°C. The amount of iridium in the earth’s crust is 1/10 million. It is often dispersed in various ores of alluvial deposits and alluvial mines together with platinum-based elements. It is rare precious metal material and belongs to the platinum family of metals. Iridium can be used in a wide range of industrial and medical applications due to its high melting point, high hardness, and corrosion resistance.

Ruthenium

Ruthenium is one of the platinum group metals. It is the least abundant of the platinum group elements in the earth’s crust and the last of the platinum group elements. Ruthenium is a rare transition metal with stable properties and high corrosion resistance, with a melting point of 2310°C and a boiling point of 3900°C, making it the highest melting point metal material in the world. It has a variety of uses and is commonly used in electronics. It is cheaper than rhodium, has very similar properties, and is commonly used to produce electrical contacts, wires, and electrodes.

Hafnium

Hafnium is a shiny silver-gray transition metal with a density of 13.31 g/cm³, a melting point of 2233°C, and a boiling point of 4603°C. It is one of the metals with the highest melting point on earth and ranks ninth among the metals with the highest melting point. in 1925, the Swedish chemist Hedwig and the Dutch physicist Kost obtained pure hafnium salts by stepwise crystallization of fluorine-containing complex salts and reduction with sodium metal to obtain pure Hafnium metal. Hafnium is rarely found in the earth’s crust and usually coexists with zirconium. Hafnium is used as an atomic energy material, alloy material, high-temperature resistant material, electronic material, etc. because of its high-temperature resistance, oxidation resistance, corrosion resistance, ease of processing, rapid heat absorption, and exotherm.

Technetium

What is a high melting point metal? Technetium is one of the metals with the highest melting point on earth, with a melting point of 2157℃ and a boiling point of 4265℃. Technetium is also the first element prepared by artificial methods. It was first obtained by bombarding molybdenum with deuterium (heavy hydrogen) in a cyclotron. The element symbol is TC. it belongs to group VIIB of the periodic table and the element is a silvery-white metal. Technetium is used as a tracer in metallurgy, low-temperature chemistry, corrosion-resistant products, nuclear fuel burn-up measurements, and medical research.

Rhodium

Rhodium is a silvery-white, hard metal that belongs to the platinum family of elements. It is also the most expensive precious metal in the world and is extremely rare. Rhodium has a higher melting point than platinum, with a melting point of 1966°C and a boiling point of 3727°C. Rhodium is insoluble in most acids, has a high melting point, and is surprisingly resistant to corrosion. This silver metal is commonly used because of its reflective properties. In addition to making alloys, it is also used as a bright and hard coating for other metals. However, due to the high price of rhodium, it is usually used only as an additive element, except for special applications.

Vanadium

Vanadium is a silvery-white metal and has one of the highest melting points of any metallic element. With a melting point of 1890°C and a boiling point of 3380°C, it has the element symbol v and belongs to the VB group in the periodic table of elements. It is known as a refractory metal along with niobium, tantalum, tungsten, and molybdenum. Among the properties of vanadium, it rarely forms as a stand-alone mineral and is mainly found in vanadium-titanium magnetite. However, world reserves of vanadium and titanium magnetite are enormous and are concentrated in a few countries and regions such as Russia, South Africa, Australia, and the United States. Vanadium is widely used in the metallurgical, aerospace, chemical, and battery industries in the form of ferrovanadium, vanadium compounds, and vanadium metal.

Why is Tantalum So Expensive?

Why is Tantalum So Expensive?

Because of the characteristics of tantalum such as good cold working and welding performance, tantalum has been used in electronics, semiconductor, chemical, machinery, aerospace, medical, and other industries.

tantalum metal

Why is Tantalum So Expensive?

Tantalum is a metal element with atomic number 73 and the chemical symbol Ta, the element corresponds to the steel gray metal, which has extremely high corrosion resistance, both in cold and hot conditions, and does not react to hydrochloric acid, concentrated nitric acid and “aqua regia”.

Tantalum is mainly found in tantalite and is symbiotic with niobium. Tantalum is moderately hard, ductile and can be drawn into thin foils of the filament type. Its coefficient of thermal expansion is very small.

Tantalum has very high chemical properties and is extremely resistant to corrosion. It can be used to make evaporating vessels, etc. It can also be used to make electrodes for electronic tubes, rectifiers and electrolytic capacitors. It is used medically to make thin sheets or threads to mend damaged tissue. Although tantalum is highly resistant to corrosion, its resistance to corrosion is due to the generation of a stable protective film of tantalum pentoxide (TaO) on its surface.

Smelting: Tantalum-niobium ores are often accompanied by a variety of metals, and the main steps in tantalum smelting are decomposition of the concentrate, purification and separation of tantalum and niobium to produce pure compounds of tantalum and niobium for the metal. Ore decomposition can be used hydrofluoric acid decomposition method, sodium hydroxide melting method and chlorination method, etc. Tantalum and niobium separation can be used solvent extraction method [commonly used extractants are methyl isobutyl ketone (MIBK), tributyl phosphate (TBP), secoctanol and acetamide, etc.], step-by-step crystallization method and ion exchange method.

Separation: First, the tantalum-niobium iron ore concentrate with hydrofluoric acid and sulfuric acid decomposition of tantalum and niobium is fluorotantalic acid and fluoronobotic acid dissolved in the leaching solution, while iron, manganese, titanium, tungsten, silicon and other associated elements are also dissolved in the leaching solution, forming a very complex composition of strong acidic solution. The tantalum-niobium leach solution is extracted with methyl isobutyl ketone and extracted into the organic phase at the same time. The pure organic phase containing tantalum-niobium is back-extracted with dilute sulfuric acid solution to obtain the organic phase containing tantalum.

Niobium and a small amount of tantalum enter the aqueous phase and then the tantalum is extracted with methyl isobutyl ketone to obtain a pure niobium-containing solution. The pure tantalum-containing organic phase is back-extracted with water to obtain a pure tantalum-containing solution.

The organic phase after the reverse extraction of tantalum is returned to the extraction cycle. Pure tantalum fluoride solution or pure niobium fluoride solution reacts with potassium fluoride or potassium chloride to form potassium tantalum fluoride (KTaF) and potassium niobium fluoride (KNbF) crystals, respectively, and can also react with ammonium hydroxide to form tantalum or niobium hydroxide precipitates.
Tantalum or niobium hydroxide is calcined at 900~1000°C to produce tantalum or niobium oxide.

Preparation of tantalum

Tantalum metal powder can be produced by the thermal reduction of metal (sodium thermal reduction) method. The reduction of potassium fluorotantalate with sodium metal in an inert atmosphere: K2TaF7+5Na─→Ta+5NaF+2KF. The reaction is carried out in a stainless steel tank, and the reduction reaction is completed rapidly when the temperature is heated to 900°C. The tantalum powder made by this method is irregular in particle shape and fine in size, which is suitable for making tantalum capacitors.

Tantalum metal powder can also be made by electrolysis of molten salt: using the molten salt of potassium fluorotantalate, potassium fluoride and potassium chloride mixture as the electrolyte to dissolve tantalum pentoxide (Ta2O5) in it, and electrolysis at 750℃, tantalum powder of 99.8~99.9% purity can be obtained.

Reduction of Ta2O5 with carbon heat can also be obtained from tantalum metal.

Reduction is generally carried out in two steps: first, a certain ratio of Ta2O5 and carbon mixture in the hydrogen atmosphere at 1800 ~ 2000 ℃ to make tantalum carbide (TaC), and then TaC and Ta2O5 in a certain ratio of the mixture of vacuum reduction into tantalum metal. Tantalum metal can also be produced by thermal decomposition or hydrogen reduction of tantalum chloride.

Dense tantalum metal can be prepared by vacuum arc, electron beam, plasma beam melting or powder metallurgy. High-purity tantalum single crystals are produced by crucible-free electron-beam regional melting.

Tantalum is a metallic element with an atomic number of 73 and the chemical symbol Ta, which corresponds to a steel-gray metal with extremely high resistance to corrosion, both in cold and hot conditions, and does not react to hydrochloric acid, concentrated nitric acid or “aqua regia”.

Tantalum is mainly found in tantalite, which is symbiotic with niobium. Tantalum is moderately hard, ductile and can be drawn into thin foil in the form of filaments. Its coefficient of thermal expansion is very small. Tantalum has very high chemical properties and is extremely resistant to corrosion. It can be used to make evaporating vessels, etc. It can also be used to make electrodes for electronic tubes, rectifiers and electrolytic capacitors.

It is used medically to make thin sheets or threads to mend damaged tissue. Although tantalum is highly resistant to corrosion, its resistance to corrosion is due to the generation of a stable protective film of tantalum pentoxide (TaO) on its surface.

What Products are Made of Tantalum?

What Products are Made of Tantalum?

Tantalum appears in many applications, including

– Sputtering barrels: Computer disk manufacturers and other industries that use sputtering processes are increasingly using tantalum to resist corrosion in sputtering barrels. The tantalum lining process is more environmentally friendly than chromium lining, helping the industry reduce its ecological impact.

tantalum

– Machined fasteners: Machined fasteners made from tantalum offer excellent corrosion resistance. They replace fasteners made from alternative materials that are prone to failure or require expensive equipment downtime for maintenance. Tantalum fasteners are found in industries such as mining, energy, and pharmaceuticals, as well as in metal and chemical processing.

– X-ray/radiation shielding: Tantalum’s radiopaque properties make it ideal for X-ray and shielding applications that seek to prevent radiation leakage. Tantalum shielding can also protect sensitive electronic components in aerospace structures as well as components operating in corrosive environments.

– Vacuum furnace heating elements: Many vacuum furnace components contain tantalum rods due to tantalum’s oxidation resistance and high melting point. Tantalum’s temperature particle stability increases the life expectancy of the machine, as it can withstand high temperatures for extended periods of time.

– Machined parts for chemical processing equipment: Tantalum’s corrosion-resistant properties make it the material of choice for machined parts for chemical processing equipment. Tantalum machined parts replace inferior materials that perform poorly in harsh chemical environments and require extensive maintenance.

 

The uses of tantalum

– 1: Tantalum carbide, used for cutting tools

– 2: Tantalum lithium, for surface acoustic waves, cell phone filters, hi-fi, and TV

– 3: Tantalum oxide, used in telescopes, cameras, lenses for cell phones and X-ray films, inkjet printers

– 4: Tantalum powder, used for tantalum capacitors in electronic circuits

– 5: Tantalum plate, used in chemical reaction equipment such as coating, valves, etc.

– 6: Tantalum wire, tantalum rod, used for repairing skeleton plates, suture frames, etc.

– 7: Tantalum ingots: used for sputtering targets, high-temperature alloys, computer hardware drive discs, and TOW-2 bomb-forming projectiles

 

Together with tungsten carbide WC and titanium carbide TIC, tantalum carbide TAC is a cemented carbide component used in cutting and drilling tools.

 

Tantalum is particularly suitable for heat exchangers; it has high thermal conductivity and its surface properties prevent the formation of adhesive deposits.

 

Manufacture of furnace components such as screens, supports, and crucibles. The alloying elements in high-temperature alloys increase high-temperature strength. It is biologically inert and can be used for implants, needles, etc. Yttrium tantalate YTAO4 is used in medical diagnostics.

 

SAM offers our customers a wide selection of tantalum rods, tubes, sheets, and wires, all designed for a variety of applications. Our products are cold rolled and annealed in a proprietary process to create machined parts with metallurgical properties ideal for applications such as sputtering gun tubes, processing into fasteners, X-ray radiation shielding, development rings, vacuum furnace heating elements, chlorinator springs, assemblies, and more for light bulbs or chemical processing equipment.

Porous Tantalum in Orthopedics

Porous Tantalum in Orthopedics

The preparation of biocompatible bony scaffolds has been one of the hot topics of research in the medical field. According to EvaluateMedTech, orthopedic-related medical devices had global sales of $36.5 billion in 2017 and will reach $47.1 billion in 2024, representing a compound annual growth rate of 3.7%.

porous tantalum

Current orthopedic metal implant materials

The choice of medical human bone implant materials, the earlier application of materials are stainless steel, nickel-chromium alloy, nickel-titanium alloy, the last 2 or 3 years the trend is TC4 titanium alloy, these materials contain nickel, chromium, or aluminum, vanadium and other harmful elements, and due to its elastic modulus exceeds the human bone too much, the material and the human body affinity is low, prone to “bone non-stick “phenomenon. Medical experts and the market are in urgent need of new non-toxic and non-hazardous new materials with good affinity to the human body to improve the current situation.

Multiple implant sizes, different clinical application scenarios

Porous tantalum has many advantages such as:

(1) Perfect integration with the host bone interface: compared to the most commonly used titanium, tantalum metal is more biocompatible and has a better osseointegration capability.

(2) Unique bionic trabecular structure: Tantalum’s elastic modulus is closer to that of bone tissue, which makes it more suitable for bionic trabecular structure in the human body than other metals.

(3) Inducing rapid bone and vascular growth into it can promote rapid growth of bone tissue and vascular tissue into the pores of porous tantalum, and its highly porous and supportive structure provides extensive space for bone growth, forming a good biological fixation, which can effectively solve the exothermic effect of bone cement and its effect on surrounding tissues, which is great clinical progress.

The above advantages make it show great clinical application value and applicability in different sizes of orthopedic implants, and different parts of bone defects.

porous tantalum application

1) Application of porous tantalum in orthopedics

In clinical applications, porous tantalum printing can be applied to all small and medium-sized restorative products. For large-sized repair products, considering the high density of pure tantalum and the excessive weight of the printed implant prosthesis, multi-component gradient printing can be adopted, with porous tantalum used in the bone growing-in area and other metals such as titanium alloy, which is cheaper and lighter in quality, being used in other areas.

With the continuous research on tantalum materials in recent years, several clinical trials have proven that new implants made of medical tantalum in combination with titanium and other metals can compensate for the shortcomings of other metal materials in terms of biocompatibility, bioactivity, and implant-bone bonding.

2) Tantalum coating – a new direction for orthopaedic applications

Tantalum metal has excellent corrosion resistance, and its coating on the surface of certain medical metal materials can effectively prevent the release of toxic elements and improve the biocompatibility of metal materials. Tantalum coatings can meet the three elements of the ideal bone graft material, namely osteoconduction, and osteogenesis, resulting in wider clinical applications and more flexible patient choices.

In addition, tantalum has also been used as an implant material in the restorative treatment of patients with missing teeth. Experiments have shown that conventional implants can absorb up to 30% of the loading energy during the loading process, while tantalum trabecular implants can absorb 50%-75%, which allows the implant to disperse the loading force to the surrounding bone during the long-term intraoral functional loading, avoiding stress concentration, while the higher friction coefficient provides good initial stability during implant placement, thus improving the dental implant bonding rate, especially in implant patients with poor bone quality.

Conclusion

Although porous tantalum is an ideal material for orthopaedic implants. However, due to the variability of the human body and the random morphology of bone defect sites, such as patients with bone tumors and patients with bone deformities, standardized porous tantalum can no longer meet the requirements of individual patient treatment. From the perspective of the development trend of clinical medicine, the best treatment method should be personalized treatment and the best implant should be a personalized implant.

Overview of Tantalum’s Main Products & Applications

Overview of Tantalum’s Main Products & Applications

Tantalum has a series of excellent properties such as high melting point, low vapor pressure, good cold workability, high chemical stability, strong resistance to liquid metal corrosion, and large dielectric constant of the surface oxide film. Therefore, tantalum is mainly used in high-tech fields such as electronics, metallurgy, steel, chemicals, hard alloys, atomic energy, superconducting technology, automotive electronics, aerospace, medical health, and scientific research.

tantalum capacitors

50% -70% of tantalum in the world is used to make tantalum capacitors in the form of capacitor-grade tantalum powder and tantalum wire. The surface of tantalum can form a dense and stable amorphous oxide film with high dielectric strength, which is easy to accurately and conveniently control the capacitor’s anodizing process.

Tantalum powder sintered blocks can obtain a large surface area in a small volume, so tantalum capacitors have high capacitance, low leakage current, low equivalent series resistance, and good high and low-temperature characteristics, long service life, and excellent comprehensive performance. Tantalum capacitors are widely used in industrial and scientific and technological sectors such as communications (exchanges, mobile phones, pagers, fax machines, etc.), computers, automobiles, home, and office appliances, instrumentation, aerospace, defense, and military.

Tantalum is an extremely versatile functional material. The following are the main products and applications of tantalum.

Tantalum carbide

Application: Cutting tools

Properties: Tantalum carbide is easy to form at high temperatures to avoid texture

Tantalum lithium

Application areas: surface acoustic waves, mobile phone filters, hi-fi and TV

Properties: strengthen the electronic signal wave, output more clear audio and video

Tantalum oxide

Applications: Lenses for telescopes, cameras and mobile phones, X-ray films, inkjet printers

Properties: Adjust the refractive index of optical glass, reduce X-ray exposure, improve image quality, and improve the wear resistance of integrated capacitors in integrated circuits

Tantalum powder

Applications: Tantalum capacitors in electronic circuits, medical devices, automotive parts such as ABS, airbag activation, engine management modules, GPS, portable electronics such as laptops, mobile phones, other devices such as flat-screen TVs, battery chargers, power diodes, Oil well probe, mobile phone signal shielding mast

Properties: high reliability, low failure rate, strong electronic storage capacity, it can withstand low temperatures such as -55 ℃ and high temperatures + 220 ℃, as well as severe vibration forces

Tantalum plate

Applications: Chemical reaction equipment such as coatings, valves, internal heat exchangers, cathodic protection systems for steel structures, water tanks, corrosion-resistant fasteners such as screws, nuts, and bolts

Properties: excellent corrosion resistance

Tantalum wire and tantalum rod

Applications: Tantalum wire and tantalum rod are used to repair hip joints, skull plates, bones after receiving tumor damage, suture clips, stent blood vessels

Properties: strong biological compatibility

Tantalum-artificial-joint

Tantalum wire and tantalum rod

Application: High-temperature furnace parts

Properties: The melting point is as high as 2996 ℃ (but vacuum protection is required)

Tantalum Disc

Application: sputtering target

Properties: a thin layer of tantalum, tantalum nitride coating oxide or semiconductor prevents copper migration

Tantalum ingot

Application: Superalloys such as jet engine vortex discs (such as blades)

Properties: The alloy composition contains 3~11% tantalum provides corrosion-resistant hot gas and allows higher operating temperature

Tantalum ingot

Application: Computer hardware driver CD

Properties: An alloy containing 6% of tantalum has shape memory properties

Stanford Advanced Materials supplies high-quality tantalum products to meet our customers’ R&D and production needs. Please visit https://www.samaterials.com/ for more information.

How is Tantalum Used in Waste Acid Recovery Equipment?

How is Tantalum Used in Waste Acid Recovery Equipment?

In the atmosphere or aqueous solution, the surface of the tantalum material will immediately form a very dense oxide film, which has a very good protective effect on the tantalum matrix, so that tantalum has extremely excellent corrosion resistance. The corrosion resistance of tantalum is similar to that of glass.

tantalum material

Except for hydrofluoric acid, fuming sulfur trioxide and concentrated sulfuric acid, concentrated phosphoric acid, and alkali at high temperature (above 180 ℃), tantalum is stable to other acids (hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid) and aqua regia (reaction rate is less than 0.01 mm/a).

Tantalum has important uses in the chemical industry and is an ideal material for the manufacture of waste acid recovery equipment, but the expensive price restricts the scale development of tantalum in the anti-corrosion industry.

Adding 2.5% tungsten to tantalum to form Ta2.5W alloy will not weaken its corrosion resistance, nor increase its density too much, but it can increase its strength. Therefore, it is possible to further roll thin-walled pipes, which can greatly reduce costs in the field of the anti-corrosion industry, and further promote the application of tantalum waste acid recovery equipment.

The development history of tantalum equipment

As early as the 1940s, developed countries already used tantalum to make waste acid treatment equipment. Tantalum is the material of choice for equipment that can handle acids other than hydrofluoric acid, so tantalum plays a significant role in industries that generate large amounts of waste acid.

Countries around the world are studying the use of tantalum’s good processability and super corrosion resistance to process waste acid recovery equipment. In the 1930s and 1940s, the United States manufactured tantalum equipment and obtained important applications in the acid industry. For example, DuPont of the United States has become one of the world’s largest tantalum equipment companies, Astro Metallurgy of the United States, BSL of France, and COMETIC of Germany have also become powerful international tantalum equipment manufacturing companies.

Tantalum waste acid recovery equipment

The exterior of the tantalum waste acid recovery equipment is made of stainless steel as a load-bearing structure; it is lined with tantalum or tantalum 2.5 tungsten plate to resist acid corrosion; its inside is a device made of tantalum tube for heating or heat exchange device.

Process of waste acid recovery

The continuous concentrated distillation process is used to recover the waste acid. The liquid enters from the back-extracted liquid inlet, and then is preheated in the second-effect chamber by gaseous water vapor and acid volatilized steam, then enters the vaporization chamber for further heating, and then enters the evaporation chamber and is coiled.

Heated by the heater, the acid and water vapor enters the second-effect chamber through the vaporization chamber, the fractionation chamber, and the connecting pipe. After the second-effect chamber is initially cooled, it enters the condensation chamber to condense into usable acid. Tantalum waste acid recovery equipment is used in the rare earth industry or acid regeneration industry. Because the recovery process of rare earth and waste acid uses a fully closed system and is a full physical process, the degree of recovery of rare earth and acid is high.

Advantages of tantalum equipment

Reasonable price evaluation is a prerequisite for the promotion and application of tantalum waste acid recovery equipment. The evaluation of economics should not only consider the original manufacturing cost but also take into account post-maintenance maintenance, spare parts, corresponding labor costs and loss of production, etc. Compared to various aspects, tantalum waste acid recovery equipment has irreplaceable advantages over other metals and non-metals in the recovery and reuse of rare earth and waste acid.

Waste acid recovery equipment made of tantalum plate and tantalum tube has a long service life and low maintenance costs for long-term use. The tantalum waste acid recovery equipment has a good process connection, which comprehensively solves the problems of salt recovery, acid regeneration, and continuous production. It can make full use of the waste heat of recycled materials, and it has an obvious energy-saving effect and good economic benefits.

Stanford Advanced Materials supplies high-quality tantalum products to meet our customers’ R&D and production needs. Please visit https://www.samaterials.com/ for more information.

What is the Trend of Ta & Nb Market?

What is the Trend of Ta & Nb Market?

The atomic sequences of tantalum (Ta) and niobium (Nb) are 73 and 41, respectively, both of which are located in the VB family of excessive elements. They are often symbiotic in nature and are important refractory rare metals. They look like steel, with off-white luster, and the powder is dark gray. They have excellent properties, including a high melting point, high boiling point, low vapor pressure, good cold workability, high chemical stability, strong resistance to liquid metal and acid and alkali corrosion, and high dielectric constant of the surface oxide film, etc.

ta trend

Tantalum and niobium metals and their compounds and alloys are important functional materials, which has important applications in the technical fields of electronics, steel, metallurgy, chemicals, hard alloys, atomic energy, aerospace, and other industrial sectors as well as strategic weapons, superconducting technology, scientific research, medical devices and so on.

Applications of tantalum and niobium

Tantalum and niobium are similar in nature and can be replaced in many application areas. However, their respective characteristics have led to the use of tantalum in industries such as electronics, metallurgy, chemicals, and hard alloys.

Electrolytic capacitors made of tantalum metals in the electronics industry have outstanding characteristics such as large capacitance, small leakage current, good stability, high reliability, good pressure resistance, long life, and small volume. They are widely used in national defense, aviation and aerospace, electronic computers, high-end civilian electrical appliances, and electronic circuits of various electronic instruments. Niobium is used in industrial-grade superconducting technology such as steel, ceramics, and nuclear energy.

In today’s world, about 65% of the total tantalum is used in the electronics industry, and about 87% of the total niobium is used in the steel industry. With the advancement of technology, the application fields of tantalum and niobium and their alloys and processed materials will continue to expand.

Tantalum can store and release energy, which is indispensable in the electronics industry, so tantalum capacitors consume more than half of the world’s mine production.

The tantalum-based components can be made very small, and other chemical elements cannot be used as substitutes without degrading the performance of the electronic device, so tantalum is almost ubiquitous as a component application, such as mobile phones, a hard disks, and a hearing aid.

In the chemical industry, the corrosion resistance of tantalum is very good and it is used as a lining for pipelines and tanks. Tantalum carbide has a high hardness and is an ideal material for manufacturing cutting tools, and tantalum oxide can increase the refractive index of glass lenses.

Current supply and demand situation

Before the end of 2011, the industry was generally operating in a benign environment. The front end of tantalum niobium production has a large space, the intermediate wet smelting and fire smelting also have a certain profit, and the back end high specific volume of tantalum powder and tantalum wire production and sales market also has a large operation space. However, since the second half of 2012, with the emergence of the global financial crisis, such applications as tantalum niobium are relatively narrow and the consumer sector has been greatly affected by the high-end electronic products industry.

The trend of the tantalum niobium market

At present, the production in the tantalum niobium industry is mainly based on wet smelting and pyrometallurgical smelting. The products produced are mainly potassium fluoroantimonate, antimony oxide, antimony oxide, antimony carbide, antimony wire, metallurgical grade tantalum powder, and some coffin materials.

At present, the domestic demand for tantalum niobium is 800~1000 tons, and the national production capacity is about 140~150 tons. Most of the rest of the raw materials are all dependent on African imports.

Most of the exported antimony mines in Africa are also known as “African blood mines”, which refer to war-plunging low-cost minerals that are arbitrarily harvested and dug in the African region at the expense of polluting the environment and destroying resources. African mines are affected by the instability of the regional political and economic environment and have greater volatility. Its products contain high levels of unfavorable elements such as antimony, uranium, and thorium, which have certain adverse effects on product quality and environmental protection requirements of downstream products; Moreover, the delivery period of the mine is long and the safety cannot be fully guaranteed. To this end, the International Electron Association has classified it as a source of minerals that are not allowed to enter the normal market.

Stanford Advanced Materials supplies high-quality tantalum niobium products to meet our customers’ R&D and production needs. Please visit https://www.samaterials.com/ for more information.

Super Performances of Tantalum in the Electronics & Aerospace Industries

Super Performances of Tantalum in the Electronics & Aerospace Industries

Tantalum has a series of excellent properties, such as high melting point, low vapor pressure, good cold processing performance, high chemical stability, as well as strong resistance to liquid metal corrosion, etc., it has important applications in high and new technology fields such as electronics, metallurgy, superconducting technology, automobile electronics, aerospace, medical treatment, and scientific research. The following is a brief introduction to the superb performances of tantalum in the electronics and aerospace industries.

tantalum powder

Electronics industry

In the electronic industry, tantalum is mainly used as tantalum capacitors, which are usually used in the form of capacitor-grade tantalum powder, tantalum wire, and tantalum foil. A tantalum capacitor is one of the indispensable electronic components of radar, aerospace aircraft and missiles, and it is widely used for civil use, such as mobile communication, electronic equipment, and instruments.

As the specific surface area of tantalum powder is large, the dielectric constant of the thin film of the dielectric body is large, so the capacitance is large, then the small large-capacity capacitors can be made. The electrolytic capacitors made of tantalum have the advantages of small size, lightweight, good reliability, wide operating temperature range, and long service life.

Tantalum electrolytic capacitors can be classified into solid electrolytic capacitors and liquid electrolytic capacitors, and they are mainly divided into two anode types: foil anode and sintered anode. Tantalum wire is used as the anode lead for both capacitors.

With the development of the electronic industry, the miniaturization and high reliability of tantalum capacitors are becoming increasingly strict. At present, the international commercial specific capacity of tantalum powder has reached more than 150,000 mu.F•V/g, and the laboratory has reached 30,000 mu.F•V/g.

Tantalum is also used as a material for electron tubes. Due to its high melting point, low real gas pressure, good processing performance, small linear expansion coefficient, and good inspiratory property, tantalum is a good material for launching tube and high-power electron tube parts.

Besides the above, tantalum target is an important material for magnetron sputtering coating of electronic chips due to its high chemical stability. You may check out more information at the specialized target website.

Aerospace industry

In addition to a large number of tantalum capacitors used in the aerospace industry, tantalum is also mainly used in high-temperature alloy and tantalum matrix heat-resistant alloy in the aerospace industry, especially in engines. High-performance alloys such as superalloy, corrosion-resistant alloy, and wear-resistant alloy can be made by adding tantalum to nickel base, cobalt base, and iron-base alloys.

Compared with niobium superalloy, tantalum superalloy has superior performance, higher heat resistance, and greater stress load. These alloys are mainly used as heat-resistant and high-strength structural materials for supersonic aircraft, solid propellant rockets, and missiles, as well as parts for control and adjustment devices. For example, the combustion chamber of the American Ajina Spacecraft is made of ta-10w alloy, and the flame temperature is very high (up to 2760℃) when its cover is small.

The aerospace industry is the second largest user of niobium and tantalum. Niobium and tantalum alloys, especially their superalloys and heat-resistant alloys based on them, are indispensable supporting materials for hot components of aircraft jet engines, rockets, spacecraft, and other vehicles.

Stanford Advanced Materials supplies high-quality tantalum products to meet our customers’ R&D and production needs. Please visit https://www.samaterials.com/ for more information.

How is Tantalum Used in the Military Industry?

How is Tantalum Used in the Military Industry?

The inner covering of the gun body

When gunpowder is exploded, it produces a tail flame with a temperature of 2500 ~ 3500K and a pressure of 300 ~ 800MPa. The tail flame contains such corrosive components as H2S, CO, O2, H2, H2O, N2, and powder residue particles. Therefore, the gun barrel will undergo the physical and chemical effects of high-temperature and high-pressure gunpowder gas (the thermal effect of high-temperature gas, the scouring of high-speed airflow, the corrosion of gunpowder gas residue in the bore, and the wear of high-speed moving projectile on the inner wall) when the projectile is launched. Under this working condition, the gun barrel bore will be subjected to severe ablative erosion and wear, which will lead to the change in the geometry and size of the barrel bore, which will directly affect the firing accuracy of the gun and the life of the barrel.

military industry

Therefore, the research on ablative behavior and protection of gun barrels has received extensive attention. The main considerations of gun barrel material are thermal properties, including heat resistance, thermal expansion, thermal conductivity, and thermal shock resistance; mechanical properties, including elastic modulus, mechanical strength, and hardness; chemical stability, that is, the chemical stability of materials in high temperature and corrosive atmosphere.

Tantalum (Ta) has good physical and chemical properties. It is a high melting point (2996℃) refractory metal, with low thermal conductivity (57W/m℃), good chemical corrosion resistance (acid, salt, and organic chemical corrosion resistance at high temperature), and excellent ablative resistance, as well as good plastic and toughness. Tantalum or tantalum alloy coating is considered to be an ideal coating system to replace the electroplating Cr coating for ablative and scour resistance. If the tantalum layer is to be used in the gun barrel for the purpose of gas ablation of fire retardant for a long time, the sputtering Ta layer should be mainly composed of alpha-ta with a thickness of at least 75 microns. The coating should have enough binding force with the substrate in all directions to resist the thermal shock and high shear stress in the gun firing process.

The cylindrical magnetron sputtering tantalum technology was proposed by Benet Laboratories of the United States army for the dimension characteristics of the gun barrel; Also, the trial production of cylindrical magnetron sputtering deposition technology platform for 120mm, 155mm, and 105mm sputtering full-length large-caliber gun tubes were built in Waterfleet Arsenal, which was used for the magnetron sputtering full-bore tantalum plating for Abrams, Crusader, and future combat systems.

In the Bennett experiment of the US army, Vigilante et al. prepared pure tantalum ablative resistant layer in a 25mm rifled gun barrel and 120mm smooth rifled gun barrel bore by using explosive spraying technology. It was found that the bonding between the tantalum layer and the base metal was good, but the adiabatic shear band would appear in the base steel of the body tube and a Ta-Fe brittle intermetallic compound phase would be formed.

Armor-piercing projectile

In the 1980s, a new type of warhead, the explosively formed penetrator, was successfully developed, mainly using tantalum on the butterfly bushing next to the high explosive. When the explosive is detonated, the butterfly disc morphs into a long, steady, sliver of a penetrator, accelerating towards its target.

With the development of armor materials, modern anti-armor warhead has higher and higher requirements on the materials of explosive forming munition type hood. The formation of a longer and more stable jet requires high density, high sound velocity, good thermal conductivity, and high dynamic fracture elongation. In addition, it is required that the material has a fine grain, low recrystallization temperature, certain texture, and other microstructure.

Tantalum and depleted uranium have high density, high dynamic elongation, and arson. Especially, tantalum has a high density (16.6g/cm3) and good dynamic characteristics, which is a kind of material mainly used in the research of explosive forming ammunition types. As a material of explosively formed munitions, tantalum is widely used in TOW-2B, TOW-NG, and other U.S. missiles. Ballistic experiments show that tantalum’s affinity is 30%~35% higher than that of copper, and can reach 150mm.

At present, the research on using tantalum as the coating material mainly focuses on improving the processing technology and saving the cost. Among them, the United States Army Equipment Research and Development Center (ARDEC) uses the P/M method to develop explosively formed tantalum cartridge type housing; Two kinds of tantalum powders, PM2 and PM4, are pressed by static pressure, sintered, extruded, and processed into blank material, and then annealed and forged by rotary forging, tantalum cartridge prepared in this way can be successfully applied to a well-shaped explosive forming projectile; German Smart-155mm end-sensitive projectile is one of the most advanced end-sensitive projectiles in the world today. The missile is made of a thin-wall structure, and its sensitive device has high anti-interference ability, which can work normally in fog or a bad environment; The BONUS-155mm dexterous shell, jointly developed by the Swedish Bofors Company and the ground weapon group, has been mass-produced and is suitable for 45-caliber artillery.

High purity materials are required for the electrochemical cover of explosive forming. Trace elements have a great influence on the physical properties of the cover material, and ultimately affect the penetration depth of the projectile. The purity of tantalum has an influence on the strength, crystal structure, and length of the explosive forming projectile (EFP). Therefore, the purity of tantalum shall be strictly controlled in the preparation process.

Ultra-high vacuum aspirating material

Ultra-high vacuum aspirating material (tantalum alloy) is used in night vision equipment in conventional defense weapons. Using 15% tantalum as the framework and titanium as the adsorbent of hydrogen, oxygen, nitrogen, carbon monoxide, carbon dioxide, water vapor, methane, neon, and other gases can improve the service life of the inspiratory material. This material can be applied to the infrared camera tube in the active infrared night-vision instrument and the low-light tube in the passive low-light night vision instrument, to ensure the long-term high vacuum in the vacuum tube, so as to achieve the high efficiency, high-life span and improve the definition of the night vision instrument.

Stanford Advanced Materials supplies high-quality tantalum products to meet our customers’ R&D and production needs. Please visit https://www.samaterials.com for more information.

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