TZM Alloy in Aerospace Applications

TZM Alloy in Aerospace Applications

What Is TZM Alloy

The aerospace industry constantly seeks materials that can withstand extreme conditions while maintaining structural integrity and performance. One such material is TZM alloy.

TZM alloy, composed of titanium (0.5%), zirconium (0.08%), carbon (0.02%), and molybdenum (balance), exhibits a range of exceptional mechanical properties that make it indispensable in aerospace engineering. The addition of titanium and zirconium improves the alloy’s strength and hardness, while the presence of carbon enhances its wear resistance. Molybdenum, being the primary component, imparts excellent high-temperature stability and thermal conductivity.

 

  • One of the most notable properties of TZM alloy is its high tensile strength, which remains significant even at elevated temperatures. It can maintain a tensile strength of approximately 690 MPa at room temperature, and about 480 MPa at 1000°C. This strength is crucial for aerospace components that must withstand extreme thermal and mechanical stresses.
  • Furthermore, TZM alloy offers superior creep resistance, which is the ability to resist deformation under prolonged exposure to high temperatures and stress. This property is vital for applications like turbine blades and rocket nozzles, where long-term stability and reliability are paramount.
  • The thermal conductivity of TZM alloy, approximately 142 W/m·K, ensures efficient heat dissipation, reducing the risk of thermal fatigue and failure. Additionally, its low coefficient of thermal expansion (about 5.3 x 10⁻⁶ /°C) minimizes thermal stress during rapid temperature changes, enhancing the durability of the components.

Related reading: TZM Alloy Applications, Properties & Preparation Methods

How Is TZM Alloy Used in the Aerospace

These exceptional mechanical properties make TZM material an essential component in aerospace engineering. Here are some specific applications:

 

  • Rocket Nozzles: TZM alloy is used in the manufacturing of rocket nozzles because it can withstand the extremely high temperatures and stresses encountered during rocket propulsion.
  • Aerospace Fasteners: Due to its strength and high-temperature stability, TZM material is used for fasteners in aerospace applications where both structural integrity and heat resistance are critical.
  • Thrust Chambers: The alloy’s ability to maintain mechanical properties at high temperatures makes it suitable for use in thrust chambers, which are exposed to high-temperature exhaust gases.
  • High-Temperature Structural Components: TZM material is used for various structural components in aerospace applications that require materials to maintain strength and stability at elevated temperatures.
  • Heat Shields: The alloy is used in heat shields to protect spacecraft from the extreme heat encountered during re-entry into the Earth’s atmosphere.
  • Turbine Blades: The high-temperature capabilities and oxidation resistance of TZM alloy make it ideal for turbine blades in jet engines, where the material is exposed to high temperatures and mechanical stresses.

Are There Any Other High-Temperature Materials?

While several materials are used in high-temperature applications, TZM alloy offers unique advantages that make it particularly suitable for aerospace uses.

 

  1. Tungsten:

Tungsten has a higher melting point and strength at high temperatures than TZM alloy. Despite tungsten’s superior heat resistance, TZM alloy is easier to machine and form, making it more practical for complex aerospace components. Additionally, TZM’s balance of high strength and lower weight is crucial for aerospace efficiency.

 

  1. Inconel:

Inconel, a nickel-chromium superalloy, is known for its oxidation and corrosion resistance at high temperatures. TZM alloy typically offers higher strength and creep resistance at extreme temperatures compared to Inconel, making it more suitable for applications like rocket nozzles and turbine blades.

 

  1. Titanium Alloys:

Titanium alloys are valued for their high strength-to-weight ratio and corrosion resistance. Although titanium alloys are lighter, TZM alloy can endure much higher temperatures without compromising its mechanical properties, making it ideal for components exposed to extreme heat.

 

  1. Ceramics:

Ceramics can withstand very high temperatures and are used in various high-heat applications. Unlike ceramics, which can be brittle and difficult to machine, TZM alloy combines high-temperature performance with better machinability and toughness, making it more versatile for aerospace component manufacturing.

Conclusion

TZM alloy’s exceptional high-temperature strength, thermal conductivity, and resistance to creep and oxidation make it indispensable in aerospace applications. Its use in rocket nozzles, gas turbine blades, heat shields, and structural components underscores its importance in ensuring the reliability and efficiency of aerospace technology.

 

Compared to other high-temperature materials, TZM alloy offers a unique combination of properties that make it an optimal choice for critical aerospace components, driving advancements and enhancing performance in this demanding field. For more details, please visit Advanced Refractory Metals (ARM).

Why is Tantalum Widely Used in Electronic Industry?

Why is Tantalum Widely Used in Electronic Industry?

Since the 1950s, TZM alloy (Mo-0.5 Ti-0.1 Zr-0.02 C) has been developed to meet the needs of the nuclear power system, aviation, and aerospace industry. It is the most widely used molybdenum alloy in the industry and the earliest refractory alloy used as a high-temperature structural material. However, the low-temperature brittleness of molybdenum alloy greatly limits its application.

tantalum metal

Tantalum metal has a lower plastic brittle transition temperature (196 ℃) and has better performance on the workability, weldability, ductility, and oxidation resistance at room temperature than that of molybdenum and tungsten in refractory metals. In addition, tantalum and its alloys with high melting point (2996 ℃), corrosion resistance, excellent high-temperature strength, and free of radioactive, etc, are widely used in the electronics industry, chemical industry, aerospace, weapon system, and the medical field, etc.

Tantalum metal
Tantalum metal

The applications of tantalum materials in the electronics industry mainly include tantalum capacitors, integrated circuits, electron tubes, memory devices, and passive devices.

Tantalum capacitor

Tantalum has the metal property of a valve, and the compact oxide film formed on its surface has unidirectional conductivity, which is suitable for making capacitors. Tantalum capacitors have a large capacity and small volume, and their capacitance is three times that of aluminum capacitors, but their volume is much smaller than that of aluminum capacitors. The working temperature of the tantalum capacitor ranges from -80 to 200 ℃, which can meet the demand of different temperatures. Besides, tantalum capacitors have strong stability and heat resistance performance and become a kind of material with high reliability in the electronics industry, which is widely used in military and high-tech fields that need to ensure high reliability.

Tantalum capacitor
Tantalum capacitor

Integrated circuit

Tantalum material is introduced into the semiconductor industry as a barrier layer thin-film material used to prevent the diffusion of copper atoms to silicon wafers. There are no compounds are formed between copper and tantalum, and copper and nitride, so tantalum and tantalum base membranes are used as barrier layers to prevent copper diffusion, and the typical thickness of the barrier layer is 0.005 ~ 0.01μm. In order to prevent the diffusion of copper atoms into the silicon matrix, tantalum nitride, tantalum silicide, tantalum carbide, and silicon nitride are used as barrier layers.

Memory device

Tantalum oxide matrix resistive memory (RRAM) has the advantages of simple structure, fast read and write speed, strong instability, and compatibility with the CMOS process. The permittivity of tantalum oxide material is very high, which is about 25. Moreover, there are only two stable phases between ta-O, Ta2O5 and TaO2, which have high oxygen capacity ratio under the high temperature of 1000 ℃.

Passive device

When tantalum nitride film is exposed to air, the surface will naturally form a layer of the oxide layer to protect the film from erosion in the presence of water vapor and voltage. The chip resistance of tantalum nitride will not cause catastrophic failure of the device due to the poor integrity of the package or protective coating.

RRAM
RRAM

When researchers discovered tantalum’s high-temperature resistance, good ductility, and corrosion resistance, the research on tantalum metal began. At present, the application field of capacitor grade tantalum wire is further expanded with the rapid development of the electronic market. However, the development of tantalum capacitors is greatly restricted due to various reasons, such as the increase in production cost, the further consumption of resources, and the intensification of the competition between ceramic and other capacitors.

In recent years, the market consumption of capacitor tantalum wire has been maintained at about 160 tons per year. With the development and use of military capacitors and the miniaturization and chip type of capacitors, the capacitor-grade tantalum wire gradually develops toward the thick and thin poles.

Please visit http://www.samaterials.com for more information.